I'm assuming the two files in the middle are the .exe files? i cannot find any files with the extension .exe directly in the name. If this is the case yes i have tried both and get the same result. And i still have the issue with the validation not retrieving mystery file.  

Quoting ringlord52,

reply 2

I'm assuming the two files in the middle are the .exe files? i cannot find any files with the extension .exe directly in the name. If this is the case yes i have tried both and get the same result. And i still have the issue with the validation not retrieving mystery file.  

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If they do not work then the issue is not with the Stardock launcher.

You might have to write to Stardock support on this one, it sounds like Sins is not starting correctly on your new rig for some reason.

Ok, so confirmed those two files in my snip are the .exe files and they do not work.

Any idea on what my missing file could be that verify cannot retrieve?

I've read through stardocks troubleshooting page for sins and i read something about a "bad .bin" file, and i cannot seem to locate a file with the extension .bin... unless its hiding from me outside of the main folder. 

Strange.

Try deleting your rebellion.user.setting file. One of the reasons the dev.exe will sometimes work but not the main executable is that the dev starts up in windows mode by default and has its own setting file. Deleting the rebellion.user.setting file will cause the game to revert back to the default settings, which might fix something like a bad resolution being saved.